Lagrangian sources of frontogenesis in the equatorial Atlantic front     

Hervé Giordani  Guy Caniaux 《Climate Dynamics》2014,43(11):3147-3162

Estimating the processes that control the north equatorial sea surface temperature (SST)-front on the northern edge of the cold tongue in the tropical Atlantic is a key issue for understanding the dynamics of the oceanic equatorial Atlantic and the West African Monsoon. Diagnosis of the frontogenetic forcings on a realistic high-resolution simulation was used to identify the processes involved in the formation and evolution of the equatorial SST-front. The turbulent forcing associated with the mixed-layer turbulent heat flux was found to be systematically frontolytic while the dynamic forcing associated with currents was found to be frontogenetic for the equatorial SST-front. Nevertheless, the low-frequency component of the turbulent forcing was frontogenetic and initiated the SST-front which was then amplified and maintained by the leading dynamic forcing. This forcing was mainly driven by the meridional convergence of the northern South Equatorial Current (nSEC) and the Guinea Current, which points out the essential role played by the circulation in the equatorial SST-front evolution. The quasi-biweekly variability of the equatorial SST-front and its forcings were found to be more strongly coupled to the wind energy flux (WEF) than to the surface wind stress. In fact the WEF controlled the convergence/divergence of the nSEC and Guinea Current and thus the meridional component of the leading dynamic forcing. The WEF explains the equatorial SST-front development better than the wind does because it is a coupled ocean-atmosphere process.  相似文献   

Influence of dispersive soil electromagnetic properties on hand‐held time domain electromagnetic sensors     

Guy Cross  Yogadhish Das 《Geophysical Prospecting》2013,61(3):658-677

Although metal detectors remain the workhorses of humanitarian demining, it is well established that the performance of both continuous wave (frequency domain) and pulsed induction (time domain) detectors can be severely compromised by so‐called ‘soil‐effects’. Generally, problem soils reduce the signal‐to‐noise ratio and increase the false‐detection rate. In certain locations, the soil‐effect is so severe as to render the detector practically inoperable. The current study is part of an ongoing international effort to establish and quantify the influence of soil electromagnetic properties on the operation of metal detectors and related sensor technologies. In particular, we examine the relative influence of soil electrical conductivity, magnetic susceptibility and associated frequency dependence on the time domain electromagnetic (TDEM) response of pulsed induction metal detectors and related small‐scale TDEM sensors.  相似文献   

Lack of relationship between Al ages of chondrules and their mineralogical and chemical compositions     

Johan Villeneuve  Marc Chaussidon  Guy Libourel 《Comptes Rendus Geoscience》2012,344(9):423-431

Previous studies have suggested the existence of a correlation between ²⁶Al relative crystallisation ages and mineralogical and bulk chemical compositions of ferromagnesian chondrules from the Bishunpur and Semarkona unequilibrated ordinary (0120 and 0150). However, because the precision in ²⁶Al ages was moderate, these correlations are questionable. Here, we report mineralogical and chemical compositions of 14 ferromagnesian chondrules from Semarkona for which precise ²⁶Al ages were previously obtained (Villeneuve et al., 2009). We find global correlation of ²⁶Al ages neither with bulk chemical composition of chondrules, nor with the different types of ferromagnesian chondrules, i.e. PO, POP and PP. This indicates that if some kind of correlations between chemical compositions of chondrules and their ages of formation exists, they do not exist at timescales that can be measured with the ²⁶Al-²⁶Mg systematics but presumably at much shorter timescales.  相似文献   

Sulfur sources of sedimentary “buckshot” pyrite in the Auriferous Conglomerates of the Mesoarchean Witwatersrand and Ventersdorp Supergroups,Kaapvaal Craton,South Africa     

B. M. Guy  S. Ono  J. Gutzmer  Y. Lin  N. J. Beukes 《Mineralium Deposita》2014,49(6):751-775

Large rounded pyrite grains (>1 mm), commonly referred to as “buckshot” pyrite grains, are a characteristic feature of the auriferous conglomerates (reefs) in the Witwatersrand and Ventersdorp supergroups, Kaapvaal Craton, South Africa. Detailed petrographic analyses of the reefs indicated that the vast majority of the buckshot pyrite grains are of reworked sedimentary origin, i.e., that the pyrite grains originally formed in the sedimentary environment during sedimentation and diagenesis. Forty-one of these reworked sedimentary pyrite grains from the Main, Vaal, Basal, Kalkoenkrans, Beatrix, and Ventersdorp Contact reefs were analyzed for their multiple sulfur isotope compositions (δ³⁴S, Δ³³S, and Δ³⁶S) to determine the source of the pyrite sulfur. In addition, five epigenetic pyrite samples (pyrite formed after sedimentation and lithification) from the Middelvlei and the Ventersdorp Contact reefs were measured for comparison. The δ³⁴S, Δ³³S, and Δ³⁶S values of all 41 reworked sedimentary pyrite grains indicate clear signatures of mass-dependent and mass-independent fractionation and range from ?6.8 to +13.8?‰, ?1.7 to +1.7?‰, and ?3.9 to +0.9?‰, respectively. In contrast, the five epigenetic pyrite samples display a very limited range of δ³⁴S, Δ³³S, and Δ³⁶S values (+0.7 to +4.0?‰, ?0.3 to +0.0?‰. and ?0.3 to +0.1?‰, respectively). Despite the clear signatures of mass-independent sulfur isotope fractionation, very few data points plot along the primary Archean photochemical array suggesting a weak photolytic control over the data set. Instead, other factors command a greater degree of influence such as pyrite paragenesis, the prevailing depositional environment, and non-photolytic sulfur sources. In relation to pyrite paragenesis, reworked syngenetic sedimentary pyrite grains (pyrite originally precipitated along the sediment-water interface) are characterized by negative δ³⁴S and Δ³³S values, suggesting open system conditions with respect to sulfate supply and the presence of microbial sulfate reducers. On the contrary, most reworked diagenetic sedimentary pyrite grains (pyrite originally precipitated below the sediment-water interface) show positive δ³⁴S and negative Δ³³S values, suggesting closed system conditions. Negligible Δ³³S anomalies from epigenetic pyrite suggest that the sulfur was sourced from a mass-dependent or isotopically homogenous metamorphic/hydrothermal fluid. Contrasting sulfur isotope compositions were also observed from different depositional environments, namely fluvial conglomerates and marine-modified fluvial conglomerates. The bulk of the pyrite grains from fluvial conglomerates are characterized by a wide range of δ³⁴S values (?6.2 to +4.8?‰) and small Δ³³S values (±0.3?‰). This signature likely represents a crustal sulfate reservoir derived from either volcanic degassing or from weathering of sulfide minerals in the hinterland. Reworked sedimentary pyrite grains from marine-modified fluvial conglomerates share similar isotope compositions, but also produce a positive Δ³³S/δ³⁴S array that overlaps with the composition of Archean barite, suggesting the introduction of marine sulfur. These results demonstrate the presence of multiple sources of sulfur, which include atmospheric, crustal, and marine reservoirs. The prevalence of the mass-dependent crustal sulfur isotope signature in fluvial conglomerates suggests that sulfate concentrations were probably much higher in terrestrial settings in comparison to marine environments, which were sulfate-deficient. However, the optimum conditions for forming terrestrial sedimentary pyrite were probably not during fluvial progradation but rather during the early phases of flooding of low angle unconformities, i.e., during retrogradational fluvial deposition, coupled in some cases with marine transgressions, immediately following inflection points of maximum rate of relative sea level fall.  相似文献   

General relativistic magnetohydrodynamic and Monte Carlo Modeling of sagittarius A*     

Guy Hilburn  Edison Liang  Siming Liu  Hui Li 《Astrophysics and Space Science》2011,331(1):145-149

Using the tunneling method we derive the Hawking temperature of the nonextremal rotating charged black hole in the Gödel universe of five-dimensional minimal supergravity theory found by Wu. We successfully recovered the tunneling probability of charged Dirac particles and the expected Hawking temperature of the black hole, which is exactly consistent with that obtained by other methods.  相似文献   

Long-term modeling of alteration-transport coupling: Application to a fractured Roman glass     

Aurélie Verney-Carron  Stéphane Gin  Guy Libourel 《Geochimica et cosmochimica acta》2010,74(8):2291-18706

To improve confidence in glass alteration models, as used in nuclear and natural applications, their long-term predictive capacity has to be validated. For this purpose, we develop a new model that couples geochemical reactions with transport and use a fractured archaeological glass block that has been altered for 1800 years under well-constrained conditions in order to test the capacity of the model.The chemical model considers three steps in the alteration process: (1) formation of a hydrated glass by interdiffusion, whose kinetics are controlled by a pH and temperature dependent diffusion coefficient; (2) the dissolution of the hydrated glass, whose kinetics are based on an affinity law; (3) the precipitation of secondary phases if thermodynamic saturation is reached. All kinetic parameters were determined from experiments. The model was initially tested on alteration experiments in different solutions (pure water, Tris, seawater). It was then coupled with diffusive transport in solution to simulate alteration in cracks within the glass. Results of the simulations run over 1800 years are in good agreement with archaeological glass block observations concerning the nature of alteration products (hydrated glass, smectites, and carbonates) and crack alteration thicknesses. External cracks in direct contact with renewed seawater were altered at the forward dissolution rate and are filled with smectites (400−500 μm). Internal cracks are less altered (by 1 or 2 orders of magnitude) because of the strong coupling between alteration chemistry and transport. The initial crack aperture, the distance to the surface, and sealing by secondary phases account for these low alteration thicknesses. The agreement between simulations and observations thus validates the predictive capacity of this coupled geochemical model and increases more generally the robustness and confidence in glass alteration models to predict long-term behavior of nuclear waste in geological disposal or natural glass in the environment.  相似文献   

DMSP and DMS dynamics and microzooplankton grazing in the Labrador Sea: application of the dilution technique     

Gordon V. Wolfe  Maurice Levasseur  Guy Cantin  Sonia Michaud 《Deep Sea Research Part I: Oceanographic Research Papers》2000,47(12):687

We adapted the dilution technique to study microzooplankton grazing of algal dimethylsulfoniopropionate (DMSP) vs. Chl a, and to estimate the impact of microzooplankton grazing on dimethyl sulfide (DMS) production in the Labrador Sea. Phytoplankton numbers were dominated by autotrophic nanoflagellates in the Labrador basin, but diatoms and colonial Phaeocystis pouchetii contributed significantly to phytomass at several high chlorophyll stations and on the Newfoundland and Greenland shelfs. Throughout the region, growth of algal Chl a and DMSP was generally high (0.2–1 d⁻¹), but grazing rates were lower and more variable, characteristic of the early spring bloom period. Production and consumption of Chl a vs. DMSP followed no clear pattern, and sometimes diverged greatly, likely because of their differing distributions among algal prey taxa and size class. In several experiments where Phaeocystis was abundant, we observed DMS production proportional to grazing rate, and we found clear evidence of DMS production by this haptophyte following physical stress such as sparging or filtration. It is possible that grazing-activated DMSP cleavage by Phaeocystis contributes to grazer deterrence: protozoa and copepods apparently avoided healthy colonies (as judged by relative growth and grazing rates of Chl a and DMSP), and grazing of Phaeocystis was significant only at one station where cells were in poor condition. Although we hoped to examine selective grazing on or against DMSP-containing algal prey, the dilution technique cannot differentiate selective ingestion and varying digestion rates of Chl a and DMSP. We also found that the dilution method alone was poorly suited for assessing the impact of grazing on dissolved sulfur pools, because of rapid microbial consumption and the artifactual release of DMSP and DMS during filtration. Measuring and understanding the many processes affecting organosulfur cycling by the microbial food web in natural populations remain a technical challenge that will likely require a combination of techniques to address.  相似文献   

Effect of macrofaunal bioturbation on bacterial distribution in marine sandy sediments, with special reference to sulphur-oxidising bacteria     

Marisol Goi-Urriza  Xavier de Montaudouin  Rmy Guyoneaud  Guy Bachelet  Rutger de Wit 《Journal of Sea Research》1999,41(4):170

We have studied the impact of the bioturbating macrofauna, in particular the lugworm Arenicola marina and the bivalve Cerastoderma edule, on abundances and distribution patterns of total bacteria and of bacteria of selected functional groups in sandy intertidal sediments. The selected groups comprised the colourless sulphur-oxidising bacteria and the anoxygenic phototrophic bacteria, which are expected to occupy small zones at the oxygen–sulphide interface in stable (non-bioturbated) sediments. The presence of a wooden wreck buried in the sediment at 10 cm depth within a large area of intertidal sand flat colonised by lugworms provided a unique opportunity to confront field observations with laboratory simulations. The site with the wooden wreck, which was used as control site, was devoid of both A. marina and C. edule, while the composition of the rest of the zoobenthic community was rather similar to that of the surrounding area. In the field, the density of total bacteria was approximately one order of magnitude higher in the control site than in the natural (bioturbated) site. This can be explained by the higher contents of silt and clay particles (higher surface-area/volume ratio) and higher total organic-carbon contents found at the control site. It appears that the presence of macrofauna affects sedimentation processes, which indirectly influence bacterial dynamics. Samples from the control site have been incubated in the laboratory with A. marina and C. edule added (bioturbated core), while an unamended core served as a control. The laboratory experiments contrasted with the field observations, because it was found that total bacteria were actually higher in the deeper layers of the bioturbated core. Moreover, the populations were more homogeneous (less stratified) and colourless sulphur bacteria were on average less numerous in the bioturbated core. In general, laboratory incubations resulted in a decrease of total bacteria with a concomitant increase of colourless and phototrophic sulphur-oxidising bacteria and thus in modifications of the bacterial community structure. Hence, our results demonstrate that care must be taken in extrapolating results from laboratory experiments (e.g. mesocosm research) to field situations.  相似文献   

Evolution of an ancient coastal plain: palaeosols, interfluves and alluvial architecture in a sequence stratigraphic framework, Cenomanian Dunvegan Formation, NE British Columbia, Canada   总被引：1，自引：0，他引：1  

Paul J. McCarthy  Ubiratan F. Faccini  & A. Guy Plint 《Sedimentology》1999,46(5):861-891

To date, discussion of changes in alluvial style and in the character of palaeosols in relation to changes in accommodation and sediment supply on floodplains has primarily been from a conceptual standpoint: few case studies are available against which to test ideas. One hundred and thirty metres of non-marine strata of the Dunvegan Formation were examined in 14 closely spaced sections in the canyon of the Kiskatinaw River, NE British Columbia, Canada. This site was located about 120 km inland from the transgressive limit of the contemporary marine shoreline and represents almost exclusively freshwater environments. Fluvial channels in the Kiskatinaw River section are of two types. Small, single-storey, very fine- to fine-grained sandstone ribbons with W/T ratios <30, encased in fine-grained floodplain sediments are interpreted as anastomosed channels. Fine- to medium-grained, laterally accreted point-bar deposits forming multistorey sand bodies with individual W/T ratios >30 are interpreted as the deposits of meandering rivers filling incised valleys. Interchannel facies include the deposits of crevasse channels and splays, lakes, floodplains and palaeosols. Floodplain palaeosols consist of laterally heterogeneous, simple palaeosol profiles and pedocomplexes similar to modern Entisols, Inceptisols and hydromorphic soils. Interfluve, sequence-bounding palaeosols adjacent to incised valleys are laterally continuous, up to 3 m thick and can be reliably identified using a combination of (1) stratigraphic position; (2) field observations, such as thickness, structure, colour, degree of rooting; and (3) micromorphological features, such as evidence of bioturbation, clay coatings, ferruginous features and sphaerosiderite. Interfluve palaeosols are similar to modern Alfisols and Ultisols. Correlation of the local stratigraphic succession with the regional sequence stratigraphic framework, based on 2340 well logs and 60 outcrop sections, shows that the vertical changes in coastal plain character (more coals and lakes vs. more pedogenesis) can be related to relatively high-frequency base level cycles (eustatic?) that are expressed as transgressive–regressive marine cycles in downdip areas. Regional isopach maps show that these cycles were progressively overprinted and modified by an increasing rate of tectonic subsidence in the north and west. The character of palaeosols developed on aggrading floodplains primarily reflects local sediment supply and drainage. In contrast, well-developed interfluve palaeosols record pedogenesis during periods of reduced or negative accommodation (base level fall). Vertical changes in floodplain palaeoenvironments and palaeosol types reflect changes in accommodation rate. The detailed micromorphological analysis of interfluve palaeosols represents a powerful application of an under-used technique for the recognition of key surfaces in the geological record. This has broad implications for non-marine sequence stratigraphy.  相似文献   

Aragonite depositional facies in a Late Ordovician calcite sea,Eastern Laurentia     

Noel P. James  Guy M. Narbonne  Alexis K. R. Armstrong 《Sedimentology》2020,67(7):3513-3532

The Black River (Upper Ordovician – Sandbian) and Trenton (Upper Ordovician – Katian) groups are traditionally interpreted as a deepening-upward succession deposited in a progressively subsiding Appalachian Basin margin that contained warm-water, marine, photozoan deposits that pass upward into cool-water, marine, heterozoan carbonates. This succession is customarily interpreted to reflect an incursion of cold, high-latitude ocean waters into the area. This view is herein confirmed for coeval carbonates in the northern part of the basin, particularly the St. Lawrence Platform. They are now well explained in this study on the basis of recent studies of cool-water carbonates and calcite–aragonite seas. Overall the succession is one of Sandbian photozoan ramp deposits succeeded by Katian heterozoan ramp carbonates that changed back to photozoan ramp deposits prior to the Hirnantian glaciation. The current interpretation, that deposition took place throughout a calcite sea time, seems at odds with this series of strata. Instead it is herein proposed that deposition took place during an aragonite sea time wherein calcite sea-like sediments accumulated under cold ocean-water temperatures. Such an interpretation is supported by recent experimental data that supports the importance of seawater temperature on CaCO₃ polymorph precipitation. If correct, this means that some of the evidence for calcite sea deposition through time brought about by global tectonics, should be re-evaluated to make sure it was not simply cool-water carbonate production.  相似文献